Synthesis and evaluation of a beta cyclodextrin-based molecularly imprinted copolymer
β Scribed by K. Sreenivasan
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 103 KB
- Volume
- 70
- Category
- Article
- ISSN
- 0021-8995
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β¦ Synopsis
A new molecularly imprinted copolymer of 2-hydroxy ethyl methacrylate (HEMA) and beta-cyclodextrin-coupled HEMA is synthesized. The copolymer is studied for its interaction with a pair of steroids, namely, cholesterol and testosterone. The molecularly imprinted copolymer is found to absorb the print molecule by several fold compared to an imprinted poly(HEMA). The enhanced absorption capacity is attributed to the presence of beta cyclodextrin moieties in the copolymer. The imprinted copolymer could be used as an adsorbent matrix.
π SIMILAR VOLUMES
Semi-interpenetrating polymer networks based on polyurethane and poly(2-hydroxy ethyl methacrylate) [poly(HEMA)] has been synthesized with memory towards cholesterol, which is induced by molecular imprinting. It is found that the polymer possesses the mechanical integrity of a typical membrane toget
2-Hydroxyethyl methacrylate (0Γ01 mol) was allowed to react with 0Γ01 mol of hexamethylene di-isocyanate and the product was coupled to 0Γ01 mol of b-cyclodextrin to form a new cyclodextrin-based copolymer. The interaction of the polymer with di β erent steroids was investigated and the extent of ads
In this study, molecular imprinting was used to develop a method based on noncovalent interactions for synthesis of a testosterone-specific polymer. The effect of the different template-monomer ratios, the particle sizes of polymers, and chromatographic mobile phases on steroid-polymer interactions
A novel molecularly imprinted polymer (MIP) system selective for D-phenylalanine is described where polymerization is performed in aqueous solution. The unique polymer system comprises a hydrophobic moiety-selective functional monomer, polymerizable b-cyclodextrin, an electrostatic interacting funct