𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis and evaluation of a beta cyclodextrin-based molecularly imprinted copolymer

✍ Scribed by K. Sreenivasan


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
103 KB
Volume
70
Category
Article
ISSN
0021-8995

No coin nor oath required. For personal study only.

✦ Synopsis


A new molecularly imprinted copolymer of 2-hydroxy ethyl methacrylate (HEMA) and beta-cyclodextrin-coupled HEMA is synthesized. The copolymer is studied for its interaction with a pair of steroids, namely, cholesterol and testosterone. The molecularly imprinted copolymer is found to absorb the print molecule by several fold compared to an imprinted poly(HEMA). The enhanced absorption capacity is attributed to the presence of beta cyclodextrin moieties in the copolymer. The imprinted copolymer could be used as an adsorbent matrix.


πŸ“œ SIMILAR VOLUMES


Synthesis and evaluation of a molecularl
✍ K. Sreenivasan πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 150 KB πŸ‘ 2 views

Semi-interpenetrating polymer networks based on polyurethane and poly(2-hydroxy ethyl methacrylate) [poly(HEMA)] has been synthesized with memory towards cholesterol, which is induced by molecular imprinting. It is found that the polymer possesses the mechanical integrity of a typical membrane toget

Synthesis and Evaluation of Ξ²-Cyclodextr
✍ Sreenivasan, K. πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 153 KB

2-Hydroxyethyl methacrylate (0Γ‰01 mol) was allowed to react with 0Γ‰01 mol of hexamethylene di-isocyanate and the product was coupled to 0Γ‰01 mol of b-cyclodextrin to form a new cyclodextrin-based copolymer. The interaction of the polymer with di †erent steroids was investigated and the extent of ads

Synthesis and binding properties of a no
✍ Soo-Hwan Cheong; Alexandre E. Rachkov; Joong-Kon Park; Kazuyoshi Yano; Isao Karu πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 163 KB πŸ‘ 1 views

In this study, molecular imprinting was used to develop a method based on noncovalent interactions for synthesis of a testosterone-specific polymer. The effect of the different template-monomer ratios, the particle sizes of polymers, and chromatographic mobile phases on steroid-polymer interactions

The rational use of hydrophobic effect-b
✍ Sergey A. Piletsky; HΓ₯kan S. Andersson; Ian A. Nicholls πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 179 KB πŸ‘ 1 views

A novel molecularly imprinted polymer (MIP) system selective for D-phenylalanine is described where polymerization is performed in aqueous solution. The unique polymer system comprises a hydrophobic moiety-selective functional monomer, polymerizable b-cyclodextrin, an electrostatic interacting funct