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Synthesis and EPR Studies of Radicals and Biradical Anions of C 60 Nitroxide Derivatives

✍ Scribed by Arena, Francesca; Bullo, Federico; Conti, Fosca; Corvaja, Carlo; Maggini, Michele; Prato, Maurizio; Scorrano, Gianfranco

Book ID
120537103
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
329 KB
Volume
119
Category
Article
ISSN
0002-7863

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Upon photo-and electrochemical in situ reduction of [ 60 ] fullerene derivatives, (n = 1, 2), C 60 [ C(COOEt) 2 ] n characteristic single-line EPR spectra are observed which are attributable to the corresponding radical anions. Monofunctionalized shows a reduction behavior similar to pristine i.e. f