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ChemInform Abstract: Synthesis and EPR Studies of Radicals and Biradical Anions of C60 Nitroxide Derivatives.

✍ Scribed by F. ARENA; F. BULLO; F. CONTI; C. CORVAJA; M. MAGGINI; M. PRATO; G. SCORRANO

Publisher: John Wiley and Sons
Year: 2010
Weight: 29 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199719122

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Upon photo-and electrochemical in situ reduction of [ 60 ] fullerene derivatives, (n = 1, 2), C 60 [ C(COOEt) 2 ] n characteristic single-line EPR spectra are observed which are attributable to the corresponding radical anions. Monofunctionalized shows a reduction behavior similar to pristine i.e. f