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Synthesis and EPR and ENDOR investigations of Coppinger's radical with perdeuteriated tert-butyl groups

✍ Scribed by J. von Gersdorff; B. Kirste; H. Kurreck

Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
409 KB
Volume
24
Category
Article
ISSN
0749-1581

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✦ Synopsis

The synthesis of Coppinger's radical (galvinoxyl) with perdeuteriated tert-butyl groups is described. Its EPR spectrum exhibits markedly decreased line widths (0.015 mT) compared with the unlabelled radical (0.039 mT). The correspondingly higher resolution allows a complete analysis of the -C hyperfine coupling constants. A comparison of the EPR and ENDOR spectra of uulabelled and of two selectively deuteriated Copginger's radicals is given.

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