Synthesis and Electronic Structure of Reduced Bis(imino)pyridine Manganese Compounds
โ Scribed by Sarah K. Russell; Amanda C. Bowman; Emil Lobkovsky; Karl Wieghardt; Paul J. Chirik
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 1023 KB
- Volume
- 2012
- Category
- Article
- ISSN
- 1434-1948
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A new spin on polymers: the title cations comprise low-spin Co(II) centers with neutral bis(imino)pyridine chelating ligands. These complexes serve as single-component ethylene polymerization catalysts and offer insight into the mechanism of chain growth and catalyst deactivation, which occurs by fo
Die Streitfrage um die Art der aktiven Spezies bei der durch Bis(imino)pyridincobalt-Verbindungen katalysierten Ethylenpolymerisation wurde von P. J. Chirik et al. beantwortet. In der Zuschrift auf S. 8293 ff. berichten sie รผber die Synthese und Charakterisierung einer Familie von Alkylkationen, die
The controversy โฆ โฆ surrounding the nature of the active species in ethylene polymerization catalyzed by bis(imino)pyridine cobalt compounds has been resolved by P. J. Chirik et al. In their Communication on page 8143 ff., they report the synthesis and characterization of a family of alkyl cations,
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