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Innentitelbild: Synthesis, Electronic Structure, and Ethylene Polymerization Activity of Bis(imino)pyridine Cobalt Alkyl Cations (Angew. Chem. 35/2011)

✍ Scribed by Crisita Carmen Hojilla Atienza; Dr. Carsten Milsmann; Dr. Emil Lobkovsky; Prof. Paul J. Chirik

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
806 KB
Volume
123
Category
Article
ISSN
0044-8249

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✦ Synopsis

Die Streitfrage um die Art der aktiven Spezies bei der durch Bis(imino)pyridincobalt-Verbindungen katalysierten Ethylenpolymerisation wurde von P. J. Chirik et al. beantwortet. In der Zuschrift auf S. 8293 ff. berichten sie über die Synthese und Charakterisierung einer Familie von Alkylkationen, die als Einzelkomponentenkatalysatoren für die Ethylenpolymerisation dienen und bei denen es sich eindeutig um Co II -Spezies handelt, die durch ligandinduzierte Homolyse von Metall-Alkyl-Bindungen desaktiviert werden.

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