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Synthesis and electrochemistry of 1,1′-bis(phosphino)cobaltocenium compounds

✍ Scribed by Kyle D. Reichl; Chelsea L. Mandell; Owen D. Henn; William G. Dougherty; W. Scott Kassel; Chip Nataro

Book ID
116680205
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
828 KB
Volume
696
Category
Article
ISSN
0022-328X

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A series of 1,8-bis(phosphino)naphthalenes 2 was prepared by treating 1,8-dilithionaphthalene with the appropriate chloro-or bromophosphines RRЈPX; R, RЈ ‫ס‬ Me (for 2a), iPr (for 2c), Cy (for 2d), Ph (for 2f); R ‫ס‬ tBu, RЈ ‫ס‬ Ph (for 2e) (X ‫ס‬ Cl) and R, RЈ ‫ס‬ Et; X ‫ס‬ Br (for 2b). The resulti