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Synthesis and Diels−Alder Reactions of a New Kind of Chiral Dienophiles: Cyclic Vinyl- p -tolylsulfilimines

✍ Scribed by García Ruano, José L.; Gamboa, Antonio Esteban; Gutiérrez, Lorena González; Martín Castro, Ana M.; Rodríguez Ramos, Jesús H.; Yuste, Francisco


Book ID
126111376
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
143 KB
Volume
2
Category
Article
ISSN
1523-7060

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By using respectively one equivalent of the pmpafgyl zinc Mcolmlate and silylated pmpargyl bromide, the preparation of 2-me/hylenc-5-trimethylsilyl-pent-4-yn-l-ol was improved. This latter is the lm~'ta'sur of the com~pcmding aldehyde whkh was used for the first time as a dienophile in [4+2] reactio