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Synthesis and deuterium labeling of some 4-phenyl, 3-substituted isochromanes

✍ Scribed by Anne-Laure Guyard; Alain Valleix; Bernard Rousseau; Jean-Christophe Cintrat

Publisher: John Wiley and Sons
Year: 2001
Tongue: French
Weight: 132 KB
Volume: 44
Category: Article
ISSN: 0022-2135
DOI: 10.1002/jlcr.484

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✦ Synopsis

Abstract

The preparation of a number of 4‐phenyl isochromanes as well as the deuterated analogs is described using a simple strategy starting from easily obtained acetals. The diasteresoselectivity and the enantioselectivity of the adopted approach are both good. The deuterated analogs are prepared using tributyltin deuteride or triethyl deuterosilane. Copyright © 2001 John Wiley & Sons, Ltd.

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