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Synthesis and cycloaddition reactions of 2-(2-thienyl)aziridines

✍ Scribed by Lown, J. W.; Matsumoto, K.


Book ID
121199463
Publisher
NRC Research Press
Year
1970
Tongue
French
Weight
559 KB
Volume
48
Category
Article
ISSN
0008-4042

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Aziridine-2,2-dicarboxylates: Synthesis,
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## Abstract Dimethyl 3‐[(4‐nitro)phenyl]aziridine‐2,2‐dicarboxylate (3a) represents a new, photochromic aziridine. 3a and related aziridines undergo cycloadditions with dipolarophiles to form five‐membered heterocycles and react with nucleophiles with cleavage of the C^2^ο£ΏC^3^ bond.