A mixture of Na,MO,, M(CO),, FeC1,.6 H,O, and (EtCO),O was heated at 120 ' C to produce the heterooctanuclear clusters Na,Fe,[M,O,-(O,CEt),], (M = Mo, 1; W, 2). The bioxo-capped clusters Na[M,O,(O,CEt),] (M, = MOW,, W,) were treated with Fe-(CO),, Cr(CO),, and Mo(CO), in (EtCO),O at 120°C to afford
✦ LIBER ✦
Synthesis and crystal structures of three novel octanuclear heterometallic clusters Na2V2[Mo3O4(OAc)8]2·H2O, Na2Cr2[Mo1.5W1.5O4(O2CEt)8]2and Na2Al2[Mo2WO4(O2CEt)8]2
✍ Scribed by Li Xu; Zaofei Li; Huang Liu; Jinshun Huang
- Publisher
- Springer
- Year
- 1996
- Tongue
- English
- Weight
- 490 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0340-4285
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