𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis, characterization and properties of two novel octanuclear heterometallic molecules consisting of two triangular molybdenum clusters bridged by oxochromium ligands: M2[Mo3O4(O2CEt)8Cr2(O2CEt)8O4Mo3] · n(HO2CEt) (M = K, n = 2; M = Li, n = 0)

✍ Scribed by Liu Huang; Li Xu; Huang Jinshun; Chen Wendan; Huang Xiaoyin; Huang Xin

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
465 KB
Volume
15
Category
Article
ISSN
0277-5387

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Syntheses, Crystal Structures, and Prope
Syntheses, Crystal Structures, and Properties of Novel Heterooctametallic Clusters Na2M'2[M3O4(O2CEt)8]2 (M' = Fe, Cr, Mo; M3 = Mo3, MoW2, W3)
✍ Li Xu; Zhaohui Li; Huang Liu; Jinshun Huang; Qianer Zhang 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 628 KB

A mixture of Na,MO,, M(CO),, FeC1,.6 H,O, and (EtCO),O was heated at 120 ' C to produce the heterooctanuclear clusters Na,Fe,[M,O,-(O,CEt),], (M = Mo, 1; W, 2). The bioxo-capped clusters Na[M,O,(O,CEt),] (M, = MOW,, W,) were treated with Fe-(CO),, Cr(CO),, and Mo(CO), in (EtCO),O at 120°C to afford