Synthesis and crystal structures of polynuclear organoaluminum-magnesium complexes and their oxidative products
β Scribed by Her, Tzong Yih; Chang, Chung Cheng; Lee, Gene Hsiang; Peng, Shie Ming; Wang, Yu
- Book ID
- 127390670
- Publisher
- American Chemical Society
- Year
- 1994
- Tongue
- English
- Weight
- 709 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0020-1669
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## Abstract Two novel chiral rhodium complexes were successfully synthesized from the reaction of chiral bidentate nitrogen ligands with RhCl~3~Β·3H~2~O in ethanol under reflux. Their unusual crystal structures were unambiguously obtained by Xβray analysis. Copyright Β© 2001 John Wiley & Sons, Ltd.
By reacting [Re(CO) 3 (Hpz) 2 (pz)] (Hpz = pyrazole) with characterized in the solid state by single crystal X-ray diffraction analysis and were showed to contain Reβ’β’β’Mn [Mn(CO) 5 Br] in toluene in the presence of Et 3 N, the dinuclear complex [(CO) 3 Re(pz) 3 Mn(CO) 3 ](Et 3 NH) (1) was interactio