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Synthesis and Crystal Structures of Lithium Complexes from the Metalation of 2-Picoline Derivatives

✍ Scribed by Leung, Wing-Por; Weng, Ling-Hong; Wang, Ru-Ji; Mak, Thomas C. W.


Book ID
127072064
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
664 KB
Volume
14
Category
Article
ISSN
0276-7333

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The mononuclear complexes [Re(CO) 3 (Hpz) 2 Br] (1) and [Re(CO) 3 (py)(Hpz)(pz)] species (6). The analogues of 4 and 6 with Hdmpz, i.e. [Re(CO) 3 (Hdmpz) 2 (dmpz)] ( ) and [Re(CO) 3 (Hdmpz) 2 Br] (2) were obtained by treating [Re(CO) 5 Br] with pyrazole (Hpz) or 3,5-dimethylpyrazole [Re(CO) 3 (py)(H