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Synthesis, characterisation and X-ray crystal structures of diorganotin(IV) complexes with 2-mercaptopyridine derivatives

✍ Scribed by M.D Couce; G Faraglia; U Russo; L Sindellari; G Valle

Publisher: Elsevier Science
Year: 1996
Tongue: English
Weight: 573 KB
Volume: 513
Category: Article
ISSN: 0022-328X
DOI: 10.1016/0022-328x(95)05985-x

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The mononuclear complexes [Re(CO) 3 (Hpz) 2 Br] (1) and [Re(CO) 3 (py)(Hpz)(pz)] species (6). The analogues of 4 and 6 with Hdmpz, i.e. [Re(CO) 3 (Hdmpz) 2 (dmpz)] ( ) and [Re(CO) 3 (Hdmpz) 2 Br] (2) were obtained by treating [Re(CO) 5 Br] with pyrazole (Hpz) or 3,5-dimethylpyrazole [Re(CO) 3 (py)(H