The reaction of the ammonia diol [(NH,)4Rh(OH)2Rh(NH,),]4' with H,O, yields among other products a peroxo-bridged dimeric species [(NH,),Rh(O,)(OH) Rh(NH,),(H,O)](ClO,),. Its structure was determined by single-crystal X-ray diffraction. The crystals are monoclinic with space group P2,/n and lattice
✦ LIBER ✦
Synthesis and crystal structures of binuclear iridium and rhodium complexes with symmetrical and unsymmetrical bulky siloxide bridges
✍ Scribed by Kownacki, Ireneusz; Kubicki, Maciej; Błażejewska-Chadyniak, Paulina
- Book ID
- 120218744
- Publisher
- Elsevier Science
- Year
- 2013
- Tongue
- English
- Weight
- 502 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0277-5387
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## Abstract Two novel binuclear nickel(II) and cobalt(III) complexes with two or three dissimilar bridges, [Ni~2~(tacn)~2~(__μ__‐N~3~)~2~(__μ__‐O~2~CPh)](ClO~4~)⋅H~2~O (1) and [Co~2~(tacn)~2~(__μ__‐N~3~)(__μ__‐OH)(__μ__‐O~2~CPh)](ClO~4~)~3~ (2) (tacn=1,4,7‐triazacyclononane), were synthesized and s