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Synthesis and Crystal Structure of ϰ-Zr9V4SH≈23.

✍ Scribed by I. Yu. Zavaliy; R. Cerny; I. V. Koval'chuck; A. B. Riabov; R. V. Denys


Publisher
John Wiley and Sons
Year
2006
Weight
9 KB
Volume
37
Category
Article
ISSN
0931-7597

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Synthesis and Crystal Structure of (PCl4
✍ A. I. Baranov; G. V. Khvorykh; S. I. Troyanov 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 83 KB 👁 2 views

The reaction between PCl 3 and ReCl 5 yielded at 200 °C the ionic tetrachlorophosphonium dirhenium nonachloride, (PCl 4 )[Re 2 Cl 9 ]. Single crystal X-ray diffraction analysis revealed a monoclinic unit cell: a = 8.616(3) A Ê , b = 10.449(4) A Ê , c = 9.397(3) A Ê , b = 99.72(3)°, V = 833.9(5) A Ê