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Synthesis and Crystal Structure of ZrP2S6and ZrP2S7

✍ Scribed by D.R. Lott; T. Fincher; G.C. LeBret; D.A. Cleary; G.L. Breneman

Publisher: Elsevier Science
Year: 1999
Tongue: English
Weight: 253 KB
Volume: 143
Category: Article
ISSN: 0022-4596
DOI: 10.1006/jssc.1998.8099

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✦ Synopsis

Two new compounds have been synthesized and characterized: ZrP 2 S 6 and ZrP 2 S 7 . Both were prepared from direct combination of the elements at high temperature using a chemical transporting agent. Single crystal X-ray diffraction and elemental analysis (ICP-AE) were performed on the materials. ZrP 2 S 6 crystallized in a tetragonal space group (P-4, a ‫؍‬ 6.6758(4) A s , c ‫؍‬ 9.491(1) A s ) whereas the ZrP 2 S 7 crystallized in a monoclinic space group (C2/c, a ‫؍‬ 8.614(1) A s , b ‫؍‬ 29.684(4) A s , c ‫؍‬ 8.583(1) A s , ‫؍‬ 120.126°°). The ZrP 2 S 6 displayed a weak second harmonic generation at 1064 nm. 1999 Academic Press

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