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Synthesis and crystal structure of [V2(μ-S2)2(S2CNEt2)4] · 2CH3Cl

✍ Scribed by Xin-Jian Lei; Fei-Long Jiang; Da-Xu Wu; Mac-Chun Hong; Zhi-Ying Huang; Han-Qin Liu


Book ID
112060125
Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
266 KB
Volume
11
Category
Article
ISSN
0256-7660

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Synthesis and Crystal Structures of the
✍ D. V. Griffiths; S. J. Parrott; M. Togrou; J. R. Dilworth; Yifan Zheng; S. Ritte 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 141 KB 👁 2 views

Novel tetrameric rhenium(V) complexes have been prepared from [ReNCl 2 (PPh 3 ) 2 ] and [ReN(PMe 2 Ph) (S 2 CNEt) 2 ], respectively. [ReNCl 2 (PPh 3 ) 2 ] reacts with 1.5 equivalents of KS 2 CNEt 2 in methanol to yield the unusual dark red species [{cyclo-ReN} 4 (S 2 CNEt 2 . The crystal structure