Synthesis and Crystal Structure of the New Quaternary Subnitride Na15Li8Ba12N6.
β Scribed by Volodymyr Smetana; Volodymyr Babizhetskyy; Grigori V. Vajenine; Arndt Simon
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 13 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
The crystal structure of a new subnitride, Na 7 Ba 14 CaN 6 , could be solved and refined based on single crystal and powder X-ray diffraction data. The compound contains Ba 14 CaN 6 clusters, which are arranged in a Na matrix as in the other subnitrides of the Na x Ba 14 CaN 6 (x = 8, 14, 17, 21, 2
## Abstract For Abstract see ChemInform Abstract in Full Text.
The future of subnitride chemistry appears promising: M~6~ octahedra with a central N atom have been detected in the new compound Na~16~Ba~6~N and in the compound hitherto described as βAg~8~Ca~3~β; the latter is actually the isotypic Ag~16~Ca~6~N (with 0.7% N)! In these compounds the M~6~N octahedr
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