Synthesis and Crystal Structure of the Dicarbido Bimetallic Cluster [CO6Ni2C2(Co)16]2−
✍ Scribed by Aurora Arrigoni; Alessandro Ceriotti; Roberto Della Pergola; Giuliano Longoni; Mario Manassero; Norberto Masciocchi; Mirella Sansoni
- Publisher
- John Wiley and Sons
- Year
- 1984
- Tongue
- English
- Weight
- 269 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0044-8249
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The compound cis-[Ni(C 6 F 5 ) 2 (PhCN) 2 ] has been used as the between [(C 6 F 5 ) 2 Ni(&µ-X) 2 Ni-(C 6 F 5 ) 2 ] 2-and L. The treatment of cis-[Ni(C 6 F 5 ) 2 (PhCN) 2 ] with [M(SAr) 2 (dppe)] leads to the starting material for the preparation of the bimetallic complexes ethane], and the Pt). Th
The crystal structures of Ni(NCNH 2 ) 4 Cl 2 and Co(NCNH 2 ) 4 Cl 2 , the first complexes with cyanamide as a neutral ligand, have been determined from single crystal data (Im3m, Z = 6, a = 1259.3(2) pm, R 1 = 0.0245 for Ni(NCNH 2 ) 4 Cl 2 and a = 1266.3(2) pm, R 1 = 0.0241 for Co(NCNH 2 ) 4 Cl 2 ;