Synthesis and crystal structure of diamagnetic ReP4, a polyphosphide with Re–Re pairs
✍ Scribed by Jeitschko, W. ;Rühl, R.
- Book ID
- 114526292
- Publisher
- International Union of Crystallography
- Year
- 1979
- Weight
- 699 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0567-7408
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The reaction between PCl 3 and ReCl 5 yielded at 200 °C the ionic tetrachlorophosphonium dirhenium nonachloride, (PCl 4 )[Re 2 Cl 9 ]. Single crystal X-ray diffraction analysis revealed a monoclinic unit cell: a = 8.616(3) A Ê , b = 10.449(4) A Ê , c = 9.397(3) A Ê , b = 99.72(3)°, V = 833.9(5) A Ê