Synthesis and Crystal Structure of Bis[(2,6-pyridinedicarboxylato) (methanol) dibenzyltin (IV)]
β Scribed by Han-Dong Yin; Chuan-Hua Wang; Yong Wang; Chun-Lin Ma
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 246 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0256-7660
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## Abstract The bis[6.3.3]propellane 6 derivative of 2,2β²,6,6β²βtetramethylbiphenyl was, in the final stage, synthesized by dehydration, of octaalcohol 5. Xβray structure analysis revealed the highly symmetric shape of the molecule and disordered oxygen atoms in the tetrahydrofuran rings. The dihedr
Bis(dicyclohexylammonium) bis(2,6-pyridinedicarboxylato)dibutylstannate is assigned seven-fold coordination at tin on the basis of its 119 Sn CP/MAS NMR chemical shift (β¦ = Οͺ 424.9 ppm). The assignment has been corroborated by a crystal structure determination of its monohydrate, whose tin atom has