The reaction of 4-amino-6-methyl-1,2,4-triazine-3(2 H)-thione-5-one (AMTTO) with silver(I) nitrate in methanol gives the complex [Ag(AMTTO) 2 ]NO 3 (1). 1 was characterized by IR and 13 C NMR spectroscopy and by an X-ray structure analysis [space group C2/c, Z = 4, lattice dimensions at Β±80 Β°C: a =
Synthesis and Crystal Structure of a New Oxovanadium(V)Multicomponent Complex with Acylhydrazone and Benzoylhydrazine
β Scribed by Yin-Zhuang Zhou; Rui-Jin Chen; Shu-Jie Tu; Xiao-Ming Lu
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 56 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0256-7660
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A new trinuclear oxovanadium(V) complex with the anionic dmpp ligand (Hdmpp = 3-hydroxy-1,2-dimethyl-4-pyridinone), [V 3 O 6 (dmpp) 3 (H 2 O)](H 2 O) 2 , was isolated from the reaction of Hdmpp, KOH and sodium metavanadate at pH 4.5. The solid state structure of the [V 3 O 6 (H 2 O)(dmpp) 3 ](H 2 O)
The reaction of 4-amino-6-methyl-1,2,4-triazine-3(2H)-thione-5-one (AMTTO, 1) with palladium(II) chloride in acetonitrile/methanol leads to the N,S-coordinated complex [Pd(g 2 -AMTTO-N,S)Cl 2 ] Β΄CH 3 OH (2). 2 has been characterized by IR and MS techniques. The ligand 1 and the complex 2 were also i
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