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Synthesis and Crystal Structure of a Chiral Complex Containing a Non-linear Heterotrimetal Chain: PtMn2(μ2-PPh2)2(CO)9

✍ Scribed by Dr. Pierre Braunstein; Dominique Matt; Dr. Odile Bars; Prof. Dr. Daniel Grandjean


Publisher
John Wiley and Sons
Year
1979
Tongue
English
Weight
243 KB
Volume
18
Category
Article
ISSN
0044-8249

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Synthesis, Structure and Reactivity of [
✍ Fernández, Eduardo J. ;Concepci Gimeno, M. ÁN ;Jones, Peter G. ;Laguna, Antonio 📂 Article 📅 1995 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 481 KB

The complex [ (acac)AuCH(PPhzAuPPh2)zCHAu( )] (1) is obtained by various procedures: a) by reaction of [Ph3PAuCH ( PPhzAuPPhz)zCHAuPPh3] ( C104)2 with NBu4 [Au( acac)Cl], b) by reaction of [CIAuCH(PPhzAuPPhz)zCHAuC1] with [Au(acac)PPh,] or with Tl(acac) and c) by reaction of [CIAuPPhzCHzPPhzAuC1] wi