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Synthesis and Structure of [(PPh3)2N][Fe3Mn(CO)12 (μ4-O)]: A Butterfly Oxo Cluster

✍ Scribed by Dr. Cynthia K. Schauer; Prof. Duward F. Shriver


Publisher
John Wiley and Sons
Year
1987
Tongue
English
Weight
257 KB
Volume
26
Category
Article
ISSN
0044-8249

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Heterometallic Nitrido-Carbonyl Clusters
✍ Roberto Della Pergola; Massimiliano Branchini; Alessandro Fumagalli; Luigi Garla 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 326 KB 👁 1 views

The anionic clusters [Fe 5 MN(CO) 14 Cp] 2-[M = Mo (1) or W (2)] were synthesized from [Fe 4 N(CO) 12 ] -and [MCp(CO) 3 ] - in refluxing acetonitrile. The clusters [Fe 3 M 3 N(CO) 18 ] 3-[M = Mo (3) or W (4)] were prepared by reaction of [Fe 4 N(CO) 12 ] - with [M 2 (CO) 10 ] 2-under the same condit