Synthesis and coordination of oxyquinolyl end-functionalized polystyrene by atom transfer radical polymerization
β Scribed by Xiang Guo; Jianmei Lu; Hua Li; Shechun Yao; Lihua Wang
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 96 KB
- Volume
- 97
- Category
- Article
- ISSN
- 0021-8995
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End-functional polystyrenes with an N,N-diethyldithiocarbamyl group were prepared by the photopolymerization of styrene with novel diethyldithiocarbamate derivatives as photoiniferters. Under ultraviolet light, the end-functional polymers could initiate a second monomer to polymerize and form block
Atom transfer radical polymerization (ATRP) was performed to prepare azide end-functional polystyrene (PSt-N 3 ) with predesigned molecular weight and narrow polydispersity. Then C 60 end-capped polystyrene was synthesized by reacting C 60 with PSt-N 3 . The UV-VIS, DSC, GPC characterizations indica