Synthesis of aromatic carboxyl functionalized polymers by atom transfer radical polymerization
✍ Scribed by Gabriel J Summers; B M Parveen Beebeejaun; Carol A Summers
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 140 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0959-8103
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Polymers prepared by atom transfer radical polymerization (ATRP) contain end groups defined by the initiator used. Alkyl halides, used as initiators, lead to polymers with an alkyl group at one end and a halide as the other chain end. Using functionalized initiators such as 2-hydroxyethyl 2-bromopro
The atom transfer radical polymerization (ATRP) of styrene has been studied using complexes of copper carboxylates. Compared with systems employing copper halides as the catalyst, the use of copper carboxylates resulted in faster polymerization rates and higher polydispersities. A ligand (dNbpy) to
Hydrolysis of 4-acetoxystyrene polymers prepared by atom transfer radical polymerization was carried out under various reaction conditions. It was found that hydrazinolysis of 4-acetoxystyrene homopolymers, random and block copolymers with styrene in 1,4-dioxane, afforded the corresponding narrow di