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Synthesis and conversion of 2-methyl-2-(3-oxobutyl)-1,3-cyclopentanedione to the isomeric racemic ketols of the [3.2.1]bicyclooctane and of the perhydroindane series

โœ Scribed by Hajos, Zoltan G.; Parrish, David R.

Book ID
111686792
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
563 KB
Volume
39
Category
Article
ISSN
0022-3263

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โœ G. Arbilla; J. C. Ferrero; E. H. Staricco ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 591 KB

The reaction of CHZ('A1) with 1,1,2,2-tetrafluorocyclopropane was studied at 300 K and a t pressures between 9.0 and 365.0 torr. Chemically activated 1-methyl-2,2,3,3-tetrafluorocyclopropane was formed and two competitive reaction paths, namely decomposition and isomerization, were observed. By fitt