Molecular mechanics (MM2) calculations have been carried out on the ten-membered ring trithioethers, I ,4,7-trithiacyclodecane (IOS3) and I ,4,. The lowest energy conformations according to these calculations are a [I3331 and a [2233] conformation, respectively. The crystal and molecular structure o
Synthesis and complexation studies of mesocyclic and macrocyclic polythioethers. 8. Synthesis and x-ray crystal structures of heavy-metal complexes of 1,5,9,13-tetrathiacyclohexadecane
β Scribed by Setzer, William N.; Tang, Yaping.; Grant, Gregory J.; VanDerveer, Donald G.
- Book ID
- 124084874
- Publisher
- American Chemical Society
- Year
- 1991
- Tongue
- English
- Weight
- 636 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0020-1669
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The mononuclear complexes [Re(CO) 3 (Hpz) 2 Br] (1) and [Re(CO) 3 (py)(Hpz)(pz)] species (6). The analogues of 4 and 6 with Hdmpz, i.e. [Re(CO) 3 (Hdmpz) 2 (dmpz)] ( ) and [Re(CO) 3 (Hdmpz) 2 Br] (2) were obtained by treating [Re(CO) 5 Br] with pyrazole (Hpz) or 3,5-dimethylpyrazole [Re(CO) 3 (py)(H
## Abstract Monosubstituted amidinate complexes [RC(NRβ²)~2~]ECl~2~ [E = Sb, R = __t__Bu, Rβ² = __i__Pr 1, Cy 2, 2,6β__i__Pr~2~C~6~H~3~ (Dipp) 3; R = __n__Bu, Rβ² = __i__Pr 4; E = Bi, R = __t__Bu, Rβ² = __i__Pr 5, Dipp 6] were prepared in high yields by salt elimination reactions of ECl~3~ with Li amid