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Synthesis and Chemistry of Highly Fluorinated Oxepane-2,7-diols.

✍ Scribed by Pamela J. Lombardi; Yonghong Gan; David M. Lemal

Book ID
101945721
Publisher
John Wiley and Sons
Year
2003
Weight
143 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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✍ Vishwakarma Singh; Punitha Vedantham; Vinayak V Kane; Kurt Polborn πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 263 KB

A new synthesis of 3-oxatricyclo[7.2.2.0 1,7 ]tridecenones via intramolecular p 4s +p 2s cycloaddition in cyclohexa-2,4dienones is described. Their photochemical reactions leading to oxepane-diquinane and oxepane-sterpurane hybrids are depicted. The crystal structure of a key intermediate is also pr