✦ LIBER ✦
Novel entry into oxepane–diquinane and oxepane–sterpurane hybrids: synthesis and photochemistry of 3-oxatricyclo[7.2.2.01,7]tridecenones
✍ Scribed by Vishwakarma Singh; Punitha Vedantham; Vinayak V Kane; Kurt Polborn
- Book ID
- 104252712
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- French
- Weight
- 263 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
A new synthesis of 3-oxatricyclo[7.2.2.0 1,7 ]tridecenones via intramolecular p 4s +p 2s cycloaddition in cyclohexa-2,4dienones is described. Their photochemical reactions leading to oxepane-diquinane and oxepane-sterpurane hybrids are depicted. The crystal structure of a key intermediate is also presented.