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Synthesis and Characterization of α,ω-Heterofunctional Poly(ethylene oxide) Macromonomers

✍ Scribed by Faruk Yilmaz; Ioan Cianga; Koichi Ito; Takamichi Senyo; Yusuf Yagci

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
82 KB
Volume
24
Category
Article
ISSN
1022-1336

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✦ Synopsis

Abstract

A novel α,ω‐heterofunctional poly(ethylene oxide) (PEO) macromonomer possessing methacryloyl and thienyl end groups was prepared by ring‐opening polymerization of ethylene oxide initiated by potassium thienylethoxide and termination of the living PEO ends with methacryloyl chloride. Incorporation of methacryloyl and thienyl groups was confirmed by free‐radical and oxidative polymerization processes, respectively, and by means of ^1^H NMR analysis.

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