## Abstract **Summary:** Based on a hydrophilic poly(ethylene oxide) macroinitiator (PEOBr), a novel amphiphilic diblock copolymer PEOβ__block__βpoly(11β(4βcyanobiphenyloxy)undecyl) methacrylate) (PEOβ__b__βPMA(11CB)) was prepared by atom transfer radical polymerization (ATRP) using CuCl/1,1,4,7,10
Synthesis and characterization of well-defined thermo- and light-responsive diblock copolymers by atom transfer radical polymerization and click chemistry
β Scribed by Tao, Xiangdong; Gao, Zhengguo; Satoh, Toshifumi; Cui, Yuan; Kakuchi, Toyoji; Duan, Qian
- Book ID
- 120386868
- Publisher
- The Royal Society of Chemistry
- Year
- 2011
- Tongue
- English
- Weight
- 209 KB
- Volume
- 2
- Category
- Article
- ISSN
- 1759-9954
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## Abstract The synthesis of diblock copolymers of aromatic polyether and polyacrylonitrile (PAN) was conducted by chainβgrowth condensation polymerization (CGCP) and atom transfer radical polymerization (ATRP) from an orthogonal initiator. When CGCP for aromatic polyether was carried out from a PA
Controlled free radical polymerization of sugar-carrying methacrylate, 3-Omethacryloyl-1,2 : 5,6-di-O-isopropylidene-D-glucofuranose (MAIpGlc) was achieved by the atom transfer radical polymerization (ATRP) technique with an alkyl halide/coppercomplex system in veratrole at 80Β°C. The time-conversion