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Synthesis and characterization of water soluble viologen linked zinc porphyrins

โœ Scribed by Yutaka Amao; Toshiaki Kamachi; Ichiro Okura


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
701 KB
Volume
98
Category
Article
ISSN
1010-6030

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A series of water-soluble viologen-linked zinc porphyrins with different methylene chain lengths (n = 3-6) between porphyrin and viologen, ZnP(C n V) 4 , were synthesized and characterized. The intramolecular electron transfer rate constants from the porphyrin moiety of ZnP(C n V) 4 to viologen were

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A series of water soluble viologen-linked trisulfonatophenylporphyrins (TPPSC,,V; n = 3-6) were synthesized. Viologen is connected with the trisulfonatophenylporphyrin via a methylene chain (-(CH,),!-: n = 3-6) in these compounds. The photochemical and electrochemical properties of TPPSC,V were inve