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Photoinduced hydrogen evolution with water soluble bisviologen linked zinc porphyrin and hydrogenase

โœ Scribed by Yutaka Amao; Toshiaki Kamachi; Ichiro Okura

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
269 KB
Volume
120
Category
Article
ISSN
1381-1169

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Photoinduced hydrogen evolution with hyd
Photoinduced hydrogen evolution with hydrogenase and water-soluble viologen-linked zinc porphyrins
โœ Yutaka Amao; Toshiaki Kamachi; Ichiro Okura ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 140 KB ๐Ÿ‘ 1 views

A series of water-soluble viologen-linked zinc porphyrins with different methylene chain lengths (n = 3-6) between porphyrin and viologen, ZnP(C n V) 4 , were synthesized and characterized. The intramolecular electron transfer rate constants from the porphyrin moiety of ZnP(C n V) 4 to viologen were