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Hydrogen evolution using photoinduced electron transfer in water soluble bisviologen-linked cationic zinc porphyrin

✍ Scribed by Yutaka Amao; Ichiro Okura

Publisher: Elsevier Science
Year: 1999
Tongue: English
Weight: 155 KB
Volume: 145
Category: Article
ISSN: 1381-1169
DOI: 10.1016/s1381-1169(99)00011-4

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A series of water-soluble viologen-linked zinc porphyrins with different methylene chain lengths (n = 3-6) between porphyrin and viologen, ZnP(C n V) 4 , were synthesized and characterized. The intramolecular electron transfer rate constants from the porphyrin moiety of ZnP(C n V) 4 to viologen were