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Synthesis and Characterization of the Thiogermanic Acids H4Ge4S10 and H2Ge4S9.

✍ Scribed by Steven A. Poling; Carly R. Nelson; Jacob T. Sutherland; Steve W. Martin


Publisher
John Wiley and Sons
Year
2003
Weight
57 KB
Volume
34
Category
Article
ISSN
0931-7597

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Ge 10 cluster, Na 4 (Ge,Si) 9 O 20 , hydrothermal. A Si modified Ge 10 cluster with structure Na 4 (Ge,Si) 9 O 20 (denoted as HUT-1) was synthesized by hydrothermal synthesis at 160 Β°C with a sodium silicate source. The compound was characterized by single crystal, powder X-ray diffraction and TGA-

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## Abstract The title compound with approximate composition Na~4~Ge~7.68~Si~1.32~O~20~ is hydrothermally prepared from a GeO~2~/xH~2~O/5en/2‐methyl pentanethylenediamine/yNaSiO~3~Β·9H~2~O (x = 35β€”46; y = 0.1β€”0.5) mixture (autoclave, 160 Β°C, 7 d) and characterized by powder and single crystal XRD.