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Synthesis and characterization of the new microporous gallophosphate Mu-8

โœ Scribed by P. Reinert; B. Marler; J. Patarin

Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
744 KB
Volume
39
Category
Article
ISSN
1387-1811

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โœฆ Synopsis

A new three-dimensional microporous gallophosphate named Mu-8 was hydrothermally synthesized in the presence of N ,N,N H ,N H -tetramethylethylenediamine as organic template. Its structure was determined from X-ray powder data by direct methods and subsequently reยฎned using the Rietveld method. The symmetry is monoclinic, space group P2 1 /c with a 9X513( 9

A and b 114X7ยฐ(3). The structure consists of gallophosphate chains of edge-sharing four rings which are connected through PO 4 tetrahedra and GaO 5 pentahedra. The resulting framework contains channels along [1 0 0] which are delimited by eight-membered ring openings. This material was also characterized by thermal analysis, 13 C and 31 P solid state NMR spectroscopy.

๐Ÿ“œ SIMILAR VOLUMES

Synthesis and structure of the new gallo
Synthesis and structure of the new gallophosphate Mu-6 containing a gallium organic complex as part of the framework
โœ P. Reinert; J. Patarin; B. Marler ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 522 KB

A new gallophosphate was synthesized in aqueous medium using the macrocycle 1,4,8,11-tetraazacyciotetradecane as organic species. The structure was determined by single crystal X-ray diffraction. The symmetry is monoclinic, space group C2/c, a=0.8842(3)nm, b=l.7781(2)nm, c=1.5805(3)nm, 13= 92.05(3)