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Synthesis and characterization of a new gallophosphate (Mu-1) containing cobalticinium cations

โœ Scribed by S. Kallus; J. Patarin; B. Marler


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
452 KB
Volume
7
Category
Article
ISSN
0927-6513

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A new three-dimensional microporous gallophosphate named Mu-8 was hydrothermally synthesized in the presence of N ,N,N H ,N H -tetramethylethylenediamine as organic template. Its structure was determined from X-ray powder data by direct methods and subsequently reยฎned using the Rietveld method. The

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A new gallophosphate was synthesized in aqueous medium using the macrocycle 1,4,8,11-tetraazacyciotetradecane as organic species. The structure was determined by single crystal X-ray diffraction. The symmetry is monoclinic, space group C2/c, a=0.8842(3)nm, b=l.7781(2)nm, c=1.5805(3)nm, 13= 92.05(3)