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Synthesis and characterization of substituted 2-diazo-1 -oxo-1,2-dihydzonaphthalenes and their products of photolysis and thermolysis

โœ Scribed by B. Baumbach; Dr. J. Bendig; T. Nagel; B. Lubsky


Book ID
105353918
Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
491 KB
Volume
333
Category
Article
ISSN
1615-4150

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โœ J.E. Franz; L.L. Black ๐Ÿ“‚ Article ๐Ÿ“… 1970 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 189 KB

The thermolysis and photolysis of various oxazoles, diazoles and triazoles 1 have'been reported (la,lb) to generate labile 1,3-dipoles (nitrenes) z which subsequently rearrange to cumulene structures 3 or react with certain dipolar-ophiles (when present) to yield 1,3-dipolar adducts 4. Z=