Synthesis and characterization of star-shaped poly(d,l-lactide)-block-poly(ethylene glycol) copolymers
✍ Scribed by Yaling Lin; Anqiang Zhang
- Publisher
- Springer
- Year
- 2010
- Tongue
- English
- Weight
- 544 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0170-0839
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## Abstract Poly(L‐lactide)‐poly(ethylene glycol) multiblock copolymers with predetermined block lengths were synthesized by polycondensation of PLA diols and PEG diacids. The reaction was carried out under mild conditions, using dicyclohexylcarbodiimide as the coupling agent and dimethylaminopyrid
## Abstract The confined crystallization behavior, melting behavior, and nonisothermal crystallization kinetics of the poly(ethylene glycol) block (PEG) in poly(L‐lactide)–poly(ethylene glycol) (PLLA–PEG) diblock copolymers were investigated with wide‐angle X‐ray diffraction and differential scanni
## Abstract **Summary:** To explore the potential of a star‐shaped 8‐armed poly(ethylene glycol)35K‐__block__‐poly(L‐lactide)37K (8‐armed PEG35K‐__b__‐PLLA37K: $\overline M \_{\rm n}$ of PEG = 35 000, $\overline M \_{\rm n}$ of PLLA = 37 000) film as a novel bioabsorbable adhesion‐prevention membra
Poly(ethylene glycol)-poly(L-lactide) diblock and triblock copolymers were prepared by ring-opening polymerization of L-lactide with poly(ethylene glycol) methyl ether or with poly(ethylene glycol) in the presence of stannous octoate. Molecular weight, thermal properties, and crystalline structure o