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Synthesis and Characterization of Several Dicopper(I) Complexes and a Spin-Delocalized Dicopper(I,II) Mixed-Valence Complex Using a 1,8-Naphthyridine-Based Dinucleating Ligand

✍ Scribed by He, Chuan; Lippard, Stephen J.


Book ID
120497210
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
134 KB
Volume
39
Category
Article
ISSN
0020-1669

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μ-η1:η1-N,N'-Imidazolidine-Bridged Dicop
✍ Manindranath Bera; Wing Tak Wong; Guillem Aromí; Debashis Ray 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 209 KB 👁 1 views

## Abstract The copper coordination chemistry of a new imidazolidine‐based doubly bridging μ‐bis(tetradentate) ligand, H~3~mhbai is studied. A new family of pentacoordinate dinuclear complexes of formula [Cu^II^~2~(‐mhbai)(‐X)]·2 H~2~O (1–4) [X = OAc, NO~3~, Cl, S~2~COMe], where H~3~mhbai stands fo