Synthesis and characterization of ruthenium (II) carbonyl complexes containing naphthyridine and acetylacetonate ligands and their catalytic activity in the hydrogen transfer reaction
✍ Scribed by Sergio A. Moya; Juan Carlos Araya; Juana Gajardo; Véronique Guerchais; Hubert Le Bozec; Loïc Toupet; Pedro Aguirre
- Book ID
- 118460415
- Publisher
- Elsevier Science
- Year
- 2013
- Tongue
- English
- Weight
- 380 KB
- Volume
- 27
- Category
- Article
- ISSN
- 1387-7003
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📜 SIMILAR VOLUMES
w Ž . x X Reaction of RuCl p-cymene with the tridentate N-N -N ligands, 2,6-pyridyl-diimines, led to substitution of 2 2 p-cymene. The resulting complexes, believed to be coordinatively unsaturated, exhibit efficient activity for the epoxidation Ž . of cyclohexene in the presence of iodosobenzene P
The reaction of 2 equiv of the optically active P, N bidentate ligands l-3 with RuC1,(PPh,)3 gives the RuCl,(l-3)2 (4-6) complexes in good yield as a mixture of isomers. The solid state structure of RuC1,( 2), (SC) is described: the two chlorine atoms are in tram position and due to steric crowding,