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Synthesis and characterization of Ru(H)2(CO)(TPPMS)3 and catalytic properties in the aqueous-biphasic hydroformylation of olefins

✍ Scribed by P.J. Baricelli; E. Lujano; M. Rodrı́guez; A. Fuentes; R.A. Sánchez-Delgado


Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
184 KB
Volume
263
Category
Article
ISSN
0926-860X

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Aqueous biphasic catalytic hydrogenation
✍ Pablo J. Baricelli; Tirza Ascanio; Eduardo Lujano; Luis G. Melean; Margarita Bor 📂 Article 📅 2007 🏛 Elsevier Science 🌐 English ⚖ 258 KB

The hydrosoluble complex [Rh(-Pz)(CO)(TPPMS)] 2 , Pz = pyrazolate ligand, and TPPMS = (C 6 H 5 ) 2 P(C 6 H 4 SO 3 Na) was used as catalytic precursor in the two phase hydrogenation reaction of the individual olefins (1-hexene, styrene, cyclohexene and 2,3-dimethyl-1-butene) to give the main expected