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Synthesis and Characterization of Rhenium−Copper Sulfide Cluster Complexes [(Ph3P)2N][Re3(CuX)(μ3-S)4Cl6(PMe2Ph)3] (X = Cl, Br, I)

✍ Scribed by Iijima, Kazuya; Sunaga, Tomoaki; Hirose, Masaya; Saito, Taro

Book ID
111688898
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
71 KB
Volume
45
Category
Article
ISSN
0020-1669

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Synthesis, Structures and Properties of Cluster Complexes [H3O(Ph3PO)3]2[Mo6Cl14] and [H(Ph3PO)2]2[Re6S6Br8]
✍ Zhyldyz S. Kozhomuratova; Yuri V. Mironov; Michael A. Shestopalov; Irina V. Dreb 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 218 KB

## Abstract New cluster compounds [H~3~O(Ph~3~PO)~3~]~2~[Mo~6~Cl~14~] (I) and [H(Ph~3~PO)~2~]~2~[Re~6~S~6~Br~8~] (II) have been prepared by the reaction of a acetonitrile solution of triphenylphosphane oxide Ph~3~PO with octahedral cluster complexes of molybdenum (H~3~O)~2~Mo~6~Cl~14~·6H~2~O and rh