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Synthesis and Characterization of Pseudotetrahedral N 2 O and N 2 S Zinc(II) Complexes of Two Heteroscorpionate Ligands: Models for the Binding Sites of Several Zinc Metalloproteins

✍ Scribed by Hammes, Brian S.; Carrano, Carl J.


Book ID
119993795
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
110 KB
Volume
38
Category
Article
ISSN
0020-1669

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The chemical behavior of two bis(3,5-dialkylpyrazol-1-yl)acetic acids and their coordination properties towards ZnCl 2 and FeCl 2 was studied. Reaction of bis(3,5-dimethylpyrazol-1-yl)acetic acid (bdmpza) (1) with ZnCl 2 and FeCl 2 gave the 2:1 complexes [(bdmpza) 2 Zn] (4) and [(bdmpza) 2 Fe] (5).