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Synthesis and Characterization of Poly(styrene- b - n -butyl acrylate- b -styrene) Triblock Copolymers Using a Dialkoxyamine as Initiator

✍ Scribed by Robin, Sophie; Guerret, Olivier; Couturier, Jean-Luc; Pirri, Rosangela; Gnanou, Yves

Book ID
120573367
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
62 KB
Volume
35
Category
Article
ISSN
0024-9297

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Triblock and pentablock copolymers of the X(Y)B(Y)X type have been synthesized by the sequential living anionic polymerization of butadiene (B), styrene (Y) and alkylmethacrylate (X), respectively. The diadduct of t-BuLi onto m-diisopropenylbenzene (m-DIB) has been used as a difunctional initiator.