Synthesis and Characterization of ω-Unsaturated Poly(styrene- b - n -butyl methacrylate) Block Copolymers Using TEMPO-Mediated Controlled Radical Polymerization
✍ Scribed by Burguière, Carine; Dourges, Marie-Anne; Charleux, Bernadette; Vairon, Jean-Pierre
- Book ID
- 127378590
- Publisher
- American Chemical Society
- Year
- 1999
- Tongue
- English
- Weight
- 146 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0024-9297
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## Abstract Radical polymerization of styrene and mixtures of styrene and 4‐vinylpyridine was performed in the presence of 2,2,6,6‐tetramethylpiperidine‐__N__‐oxyl (TEMPO) producing polymers with controlled molecular weights and molecular weight distributions. The living nature of these polymers wa
## Abstract Poly(__n__‐butyl methacrylate) (PBMA)‐__b__‐polystyrene (PSt) diblock copolymers were synthesized by emulsion atom transfer radical polymerization (ATRP). PBMA macroinitiators that contained alkyl bromide end groups were obtained by the emulsion ATRP of __n__‐butyl methacrylate with BrC