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Synthesis and characterization of poly(benzobisthiazole) with tetramethylbiphenyl moiety in the main chain

✍ Scribed by Xiaodong Hu; Satish Kumar; Malcolm B. Polk; D. L. Vanderhart

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
506 KB
Volume
36
Category
Article
ISSN
0887-624X

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✦ Synopsis

Poly(benzobisthiazole)s containing an ortho-tetramethyl substituted biphenyl moiety were synthesized via the polycondensation of 2,5-diamino-1,4-benzenedithiol dihydrochloride with 2,2 ,6,6-tetramethylbiphenyl-4,4 -dicarboxylic acid in poly(phosphoric acid) (PPA). The intrinsic viscosities of the tetramethylbiphenyl poly-(benzobisthiazole)s in chlorosulfonic acid at 30ЊC were in the range of 6.9-13.4 dL/g. Copolycondensation of 2,5-diamino-1,4-benzenedithiol dihydrochloride with terephthalic acid and 2,2 ,6,6-tetramethylbiphenyl-4,4 -dicarboxylic acid was carried out as well by varying the ratio of the two dicarboxylic acid monomers in the reactant mixture. The homopolymers and copolymers were characterized by Fourier transform infrared spectroscopy (FTIR) and 13 C solid-state nuclear magnetic resonance spectroscopy (NMR). Thermal stability of the polymers was evaluated by thermogravimetric analysis (TGA) and thermogravimetric mass spectrum analysis (TG-MS). The tetramethylbiphenyl poly(benzobisthiazole)s were found to be more stable at elevated temperatures than the parent poly( p-phenylene benzobisthiazole) (PBZT).

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